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DOI: 10.1039/A702765F (Paper) Reference Section for: Chem. Commun., 1997, 1543-1544

One- and two-dimensional organic–inorganic composite solids constructed from molybdenum oxide clusters and chains linked through {M(2,2′-bpy)}2+ fragments (M = Co, Ni, Cu)

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Pamela J. Zapf, Christopher J. Warren, Robert C. Haushalter and Jon Zubieta

Abstract

Hydrothermal reactions of Na2MoO4·2H2O and MoO3 with MCl2·xH2O (M = Co, Ni, Cu) and 2,2′-bipyridine yield one- and two-dimensional solids, characterized by molybdenum oxide monomers, clusters and chains linked by {M(2,2′-bpy)}2+ groups and represented by the formulae [M(bpy)x- (H2O)yMonO3n +1] (n = 2, M = Cu, x= 1, y = 0; n = 3, M = Co, x = 1, y = 0; n = 4, M = Ni, x = 2, y = 0).

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