First example of a copper(i)–water bond. Synthesis and structure of polymeric poly-µ-2,3-diphenylquinoxaline–(aqua)copper(i) cation

(Note: The full text of this document is currently only available in the PDF Version )

Jnan P.N askar, Sanchita Hati, Dipankar Datta and Derek A. Tocher


Abstract

The perchlorate salt of the poly-µ-2,3-diphenylquinoxaline(aqua)copper(I) cation containing a discrete Cu+–OH2 bond is synthesised and characterised structurally.


References

  1. R. G. Pearson, Inorg. Chim. Acta, 1995, 240, 93 CrossRef CAS and references therein.
  2. B. Douglas, D. McDaniel and J. Alexander, Concepts and Models of Inorganic Chemistry, 3rd edn., Wiley, New York, 1994, pp. 337–343 Search PubMed.
  3. S. Hati and D. Datta, Proc. Indian Acad. Sci. (Chem. Sci.), 1996, 108, 143 Search PubMed and references therein.
  4. D. Datta, Indian J. Chem., Sect. A, 1987, 26, 605 and references therein.
  5. B. J. Hathaway, in Comprehensive Coordination Chemistry: The Synthesis, Reactions, Properties and Applications of Coordination Compounds, ed. G. Wilkinson, Pergamon, Oxford, 1987, vol. 5, ch. 53 Search PubMed.
  6. A. R. Ahmed, L. K. Mehta and J. Parrick, J. Chem. Soc., Perkin Trans. 1, 1996, 2443 RSC.
  7. S. Hati and D. Datta, J. Chem. Soc., Dalton Trans., 1995, 1177 RSC.
  8. J. P. Naskar, S. Hati and D. Datta, Acta Crystallogr., Sect. B, in press Search PubMed.
  9. M. Munakata, S. Kitagawa and T. Emori, J. Chem. Soc., Chem. Commun., 1991, 1244 RSC.
  10. M. Munakata, T. Kuroda-Sowa, M. Maekawa, M. Nakamura, S. Akiyama and S. Kitagawa, Inorg. Chem., 1994, 33, 1284 CrossRef CAS.
  11. G. M. Sheldrick, SHELXS-86, Program for crystal structure solution, Acta Crystallogr., Sect. A, 1990, 46, 467 Search PubMed.
  12. G. M. Sheldrick, SHELXL-93, University of Göttingen, 1993.
Click here to see how this site uses Cookies. View our privacy policy here.