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DOI: 10.1039/A702560B (Paper) Reference Section for: Chem. Commun., 1997, 1127-1128

Fluorous-phase soluble rhodium complexes: X-ray structure of [RhCl(CO)(P(C2H4C6F13)3 )2]

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John Fawcett, Eric G. Hope, Raymond D. W. Kemmitt, Danny R. Paige, David R. Russell, Alison M. Stuart, David J. Cole-Hamilton and Marc J. Payne

Abstract

Rhodium(I) complexes of the ligands P(CH2CH2C6F13)3 and P(C6H4C6F13-4)3, which can be compared to their perprotio analogues, maintain their structures in fluorous solvents.

References

  1. I. T. Horváth and J. Rábai, Science, 1994, 266, 72 CrossRef CAS; US Pat., 5,463,082, 1995 Search PubMed.
  2. D. P. Curran and S. Hadida, J. Am. Chem. Soc., 1996, 118, 2531 CrossRef CAS; D. P. Curran and M. Hoshino, J. Org. Chem., 1996, 61, 6480 CrossRef CAS.
  3. G. Pozzi, S. Banfi, A. Manfredi, F. Montanari and S. Quici, Tetrahedron, 1996, 52, 11 879 CrossRef CAS.
  4. M. J. Atherton, K. S. Coleman, J. Fawcett, J. H. Holloway, E. G. Hope, A. Karaçar, L. A. Peck and G. C. Saunders, J. Chem. Soc., Dalton Trans., 1995, 4029 RSC; J. H. Holloway, E. G. Hope, D. R. Russell, G. C. Saunders and M. J. Atherton, Polyhedron, 1996, 15, 173 CrossRef CAS; M. J. Atherton, J. Fawcett, J. H. Holloway, E. G. Hope, A. Karaçar, D. R. Russell and G. C. Saunders, J. Chem. Soc., Dalton Trans., 1996, 3215 RSC.
  5. P. Bhattacharya, D. Gudmunsen, E. G. Hope, R. D. W. Kemmitt, D. R. Paige and A. M. Stuart, in preparation.
  6. J. Chatt and B. L. Shaw, J. Chem. Soc., A, 1966, 1437 RSC; B. E. Mann, C. Masters and J. Chatt, J. Chem. Soc., A, 1971, 1104 RSC.
  7. See for example: A. Monae, E. Gutierrez-Puebla, J. V. Heras and E. Pinilla, Acta Crystallogr. Sect. C, 1983, 39, 446 Search PubMed; A. Ceriotti, G. Ciani and A. Sironi, J. Organomet. Chem., 1983, 247, 345 CrossRef; R. L. Harlow, S. A. Westcott, D. L. Thorn and R. T. Baker, Inorg. Chem., 1992, 31, 323 CrossRef CAS.
  8. S. E. Boyd, L. D. Field, T. W. Hambley and M. G. Partridge, Organometallics, 1993, 12, 1720 CrossRef CAS.
  9. N. A. Cruise and J. Evans, J. Chem. Soc., Dalton Trans., 1995, 3089 RSC; D. Bogg, M. Conyngham, J. M. Corker, A. J. Dent, J. Evans, R. C. Farrow, V. L. Kambhampati, A. F. Masters, D. N. McLeod, C. A. Ramsdale and G. Salvini, Chem. Commun., 1996, 647 RSC.
  10. S. A. Brewer, A. K. Brisdon, J. H. Holloway, E. G. Hope, L. A. Peck and P. G. Watson, J. Chem. Soc., Dalton Trans., 1995, 2945 RSC.
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