Anodic co-oxidation of urazole and ferrocenes: first trapping of cyclopentadienols

(Note: The full text of this document is currently only available in the PDF Version )

Jocelyn Lorans, Fabrice Pierre, Loïc Toupet and Claude Moinet


Abstract

Cyclopentadien-5-ols, the major products resulting from decomposition of some ferrocenium cations by molecular oxygen, are regio- and stereo-selectively trapped by 4-phenyl-1,2,4-triazoline-3,5-dione.


References

  1. W. P. Fehlhammer and C. Moinet, J. Electroanal. Chem. Interfacial Electrochem., 1983, 158, 187 CrossRef CAS.
  2. E. Fahr and H. Lind, Angew. Chem., Int. Ed. Engl., 1966, 5, 372 CrossRef CAS.
  3. K. MacKenzie, in The Chemistry of the Hydrazo, Azo and Azoxy Groups, ed. S. Patai, Wiley, New York, 1975, ch. 11 Search PubMed.
  4. G. Bianchi, C. De Micheli and R. Gandolfi, in The Chemistry of the Double Bonded Functional Groups, ed. S. Patai, Wiley, New York, 1977, part 1, ch. 6 Search PubMed.
  5. M. Quinteiro, C. Seoane and J. L. Soto, Heterocycles, 1978, 9, 1771 CAS.
  6. C. J. Moody, Azo Dicarbonyl Compounds Advances in Heterocyclic Chemistry, Academic Press Inc., 1982, vol. 30 Search PubMed.
  7. R. A. Clement, J. Org. Chem., 1960, 25, 1724 CrossRef CAS; 1962, 27, 1115.
  8. R. C. Cookson, S. S. H. Gilani and I. D. R. Stevens, Tetrahedron Lett., 1962, 14, 615 CrossRef; J. Chem. Soc., C, 1967, 1905 Search PubMed.
  9. E. F. Ullman and E. A. Barktus, Chem. Ind., 1962, 93 Search PubMed.
  10. T. J. Kealy, J. Am. Chem. Soc., 1962, 84, 966 CrossRef CAS.
  11. J. Sauër and B. Schröder, Angew. Chem., Int. Ed. Engl., 1965, 4, 711.
  12. C. Moinet and E. Raoult, Bull. Soc. Chim. Fr., 1991, 214 CAS.
  13. F. Turecek, J. Org. Chem., 1986, 51, 1563 CrossRef.
  14. K. Alder and F. H. Flock, Chem. Ber., 1956, 1732 CAS.
  15. C. Moinet, unpublished results.
Click here to see how this site uses Cookies. View our privacy policy here.