DOI: 10.1039/A702505J
(Paper)
Reference Section for: Chem. Commun., 1997, 1169-1170
Generation and inter- and intra-molecular trapping of isoindenones (inden-2-ones)
(Note: The full text of this document is currently only available in the PDF Version )
David W. Jones and Tracie C. L. M. Ryder
Abstract
Inden-2-one and some simple derivatives are smoothly generated by reaction of caesium fluoride with 1-bromo-2-tert-butyldimethylsilyloxyindenes and they can be efficiently trapped in both intra- and inter-molecular additions; the intramolecular additions proceed with exo-addition of the tether, in contrast to the intermolecular additions and intramolecular additions to 2-benzopyran-3-ones.
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