A tetranuclear cluster sandwiched between edge-bridging cycloheptatrienyl rings: the synthesis and characterisation of [Ru4(CO)7(µ-C7H7)2 ]

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Dario Braga, Paul J. Dyson, Fabrizia Grepioni, Brian F. G. Johnson, Caroline M. Martin, Laura Scaccianoce and Alexander Steiner


Abstract

The reaction of [Ru3(CO)12] with cycloheptatriene affords [Ru4(CO)7(µ-C7H7)2 ] an example of a new class of sandwich cluster which is characterised in the solid-state by single-crystal X-ray diffraction and shown to contain an unusual arrangement of two parallel edge-bridging organic rings.


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