Synthesis of the LTA-type AlPO4 in the presence of the diazapolyoxa macrocycle ‘Kryptofix 222’

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L. Schreyeck, F. D’agosto, J. Stumbe, P. Caullet and J. C. Mougenel


Abstract

The LTA-type aluminophosphate can be synthesized from aqueous mixtures in the presence of a single structuring agent, hexaoxa-4,7,13,16,21,24-diaza-1,10-bicyclo[8,8,8]hexacosane (possibly associated with F- ion as optional co-template) and is characterized through XRD, SEM, chemical analysis, thermal analysis and solid-state NMR spectroscopy.


References

  1. T. B. Reed and D. W. Breck, J. Am. Chem. Soc., 1956, 78, 5972 CrossRef CAS.
  2. R. M. Barrer and P. J. Denny, J. Chem. Soc., 1961, 971 RSC.
  3. G. T. Kerr, Inorg. Chem., 1966, 5, 1537 CrossRef CAS.
  4. R. L. Wadlinger, E. J. Rosinski and C. J. Planck, US Pat., 3375205, 1968 Search PubMed.
  5. G. H. Kühl, Inorg. Chem., 1971, 10, 2488 CrossRef.
  6. B. M. Lok, C. A. Messina, R. L. Patton, R. T. Gajek, T. R. Cannan and E. M. Flanigen, US Pat., 4440871, 1984 Search PubMed.
  7. A. Merrouche, J. Patarin, M. Soulard, H. Kessler and D. Anglerot, Molecular Sieves—Synthesis of Microporous Inorganic Materials, Van Nostrand Reinhold, New York, vol. 1, 1992, p. 384 Search PubMed.
  8. L. Sierra, C. Deroche, H. Gies and J. L. Guth, Microporous Mater., 1994, 3, 29 CrossRef CAS.
  9. C. Schott-Darie, J. Patarin, P. Y. Le Goff, H. Kessler and E. Benazzi, Microporous Mater., 1994, 3, 123 Search PubMed.
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