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DOI: 10.1039/A702197F (Paper) Reference Section for: Chem. Commun., 1997, 1665-1666

Hydrolysis of an iridium–methyl bond, formation of trans-[Ir(CO)(OH)L2] from trans-[Ir(CO)MeL2] [L = PPh2(m-C6H4SO3Na), PPh2(m-C6H4SO3K) or P(C6H4SO3Na)3] upon dissolving in water

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David P. Paterniti and Jim D. Atwood

Abstract

The synthesis, characterization and rapid hydrolysis of trans-[Ir(CO)MeL2] (L = a water-soluble phosphine) to trans-[Ir(CO)(OH)L2] and CH4 are reported.

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