Ionic liquid–polymer gel catalytic membrane

(Note: The full text of this document is currently only available in the PDF Version )

Richard T. Carlin and Joan Fuller


Abstract

A novel catalytic membrane for heterogeneous hydrogenation is fabricated by incorporating palladium into a gas-permeable ionic liquid–polymer gel composed of 1-n-butyl-3-methylimidazolium hexafluorophosphate and poly(vinylidene fluoride)–hexafluoropropylene copolymer.


References

  1. J. Fuller, A. C. Breda and R. T. Carlin, J. Electrochem. Soc., 1997, 144, L69.
  2. E. I. Cooper and E. J. M. O'Sullivan, in Proceedings of the 8th International Symposium on Molten Salts, ed. R. J. Gale, G. Blomgren and H. Kojima, The Electrochemical Society Proceedings Series, Pennington, NJ, 1992, PV 92-16, p. 386 Search PubMed; J. S. Wilkes and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1992, 965 Search PubMed; J. Fuller, R. T. Carlin, H. C. De Long and D. Haworth, J. Chem. Soc., Chem. Commun., 1994, 299 RSC; R. T. Carlin, H. C. De Long, J. Fuller and P. C. Trulove, J. Electrochem. Soc., 1994, 141, L73 RSC; P. Bonhôte, A.-P. Dias, N. Papageorgiou, K. Kalyanasundaram and M. Grätzel, Inorg. Chem., 1996, 35, 1168 CAS.
  3. J. Fuller and R. T. Carlin, J. Electroanal. Chem., submitted Search PubMed.
  4. Y. Chauvin, L. Maussmann and H. Olivier, Angew. Chem., Int. Ed. Engl., 1995, 34, 2698 CrossRef; Y. Chauvin and H. Olivier-Bourbigou, CHEMTECH, 1995, 25, 26 CAS.
  5. M. P. Harold, C. Lee, A. J. Burggraaf, K. Keizer, V. T. Zaspalis and R. S. A. de Lange, MRS Bull., 1994, 4, 34 Search PubMed.
  6. G. P. Pez, R. T. Carlin, D. V. Laciak and C. Sorenson, US Pat., 4,761,164 Search PubMed.
  7. For reviews see: R. M. Pagni, in Advances in Molten Salt Chemistry, ed. G. Mamantov, C. B. Mamantov and J. Braunstein, Elsevier, Amsterdam, 1987, vol. 6, p. 211 Search PubMed; R. A. Osteryoung, in Molten Salts Chemistry, ed. G. Mamantov and R. Marrasi, NATO ASI, Series C, Mathematical and Physical Sciences, D. Reidel, Dordrecht, 1987, vol. 202, p. 329 Search PubMed; C. L. Hussey, in Advances in Non-aqueous Chemistry, ed. G. Mamantov and A. Popov, VCH, New York, 1994, ch. 4, p. 227 Search PubMed; R. T. Carlin and J. S. Wilkes, in Advances in Non-aqueous Chemistry, ed. G. Mamantov and A. Popov, VCH, New York, 1994, ch. 5, p. 277 Search PubMed.
  8. R. T. Carlin and J. Fuller, Inorg. Chim. Acta, 1997, 255, 189 CrossRef CAS.
  9. J. K. D. Surette, L. Green and R. D. Singer, Chem. Commun., 1996, 2753 RSC.
Click here to see how this site uses Cookies. View our privacy policy here.