Atom transfer radical polymerisation (ATRP) of methyl methacrylate in the presence of radical inhibitors

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D. M. Haddleton, A. J. Clark, M. C. Crossman, D. J. Duncalf, A. M. Heming, S. R. Morsley and A. J. Shooter


Abstract

Atom transfer radical polymerisation of methyl methacrylate mediated by copper(I) bromide, alkyl bromides and N-pentyl-2-pyridylmethanimine has been shown to be enhanced by the addition of substituted phenols, traditionally used as radical inhibitors.


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