Zirconaindane phospholanes: key reagents for the synthesis of mono- or tri-cyclic phosphanes and related species

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M. Zablocka, A. Igau, B. Donnadieu, J.-P. Majoral, A. Skowronska and P. Meunier


Abstract

The zirconaindane phospholane 3 reacts either with PhSbCl2 or Me2SnCl2 to give tricyclic systems incorporating phosphorus, antimony or tin; the same reaction involving 3 and R2PCl (R = Ph, Et) leads to acyclic–cyclic diphosphanes.


References

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