A new and efficient synthesis of rosefuran. A general synthesis of
furans by palladium-catalysed cycloisomerization of
(Z)-2-en-4-yn-1-ols
(Note: The full text of this document is currently only available in the PDF Version )
Bartolo Gabriele and Giuseppe Salerno
Abstract
(Z)-3,7-Dimethylocta-2,6-dien-4-yn-1-ol, readily available
from (Z)-3-methylpent-2-en-4-yn-1-ol, undergoes
cycloisomerization in the presence of catalytic amounts of
K2PdI4 to give rosefuran in high yield.
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