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DOI: 10.1039/A701552F (Paper) Reference Section for: Chem. Commun., 1997, 959-960

Room-temperature oxidation of 2-aminobenzoyl- to 2-aminobenzoato-palladium(ii) complexes and of coordinated PPh3 by atmospheric oxygen; X-ray crystal structure of [(PPh3)2P[upper bond 1 start]d(NH2C6H 4CO[upper bond 1 end]2-2)Pd[upper bond 1 start]{C(O)C6H 4N[upper bond 1 end]H2-2}(PPh3)]O3 SCF3

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José Vicente, José-Antonio Abad, Andrew D. Frankland and M.-Carmen Ramírez de Arellano

Abstract

trans-[Pd(C6H4NH2-2)I(PPh 3)2] reacts with CO to give the insertion product trans-[Pd{C(O)(C6H4NH2-2) }(PPh3)2]O3SCF3 or, in the presence of atmospheric oxygen, [(PPh3)2- Pd(NH2C6H4CO2-2)Pd{C(O)C 6H4NH2-2}(PPh3)]O3 SCF3, whose crystal structure is solved.

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