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DOI: 10.1039/A701227F (Paper) Reference Section for: Chem. Commun., 1997, 869-870

Use of electrospray ionization mass spectrometry to characterize chiral reactive intermediates in a titanium alkoxide mediated sulfoxidation reaction

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Marcella Bonchio, Giulia Licini, Giorgio Modena, Stefano Moro, Olga Bortolini, Piero Traldi and William A. Nugent

Abstract

The ESIMS technique, combined with 1H NMR evidence, provides a precise inventory of the catalytic TiIV precursors and the characterization of the reactive peroxometal complex involved in enantioselective sulfoxidation employing the TiIV–homochiral trialkanolamine–alkylhydroperoxide system.

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