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DOI: 10.1039/A701143A (Paper) Reference Section for: Chem. Commun., 1997, 1249-1250

Novel gold derivatives of titanium carbonyl and structural characterization of a compound containing an unsupported gold–titanium bond: [Ti(CO)6(AuPEt3)]-

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Paul J. Fischer, Victor G. Young Jr. and John E. Ellis

Abstract

Hexacarbonyltitanate(2-) reacts with (R3P)AuCl (R = C6H11, Et) to provide the first anions of the general formula [M(CO)x(AuPR3)y] z, and a structurally characterized (for R = Et) compound containing a largely unsupported gold–titanium bond.

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