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DOI: 10.1039/A700884H (Paper) Reference Section for: Chem. Commun., 1997, 979-980

Synthesis, X-ray structure and electrochemical characterisation of a binuclear thiolate bridged Ni–Fe–nitrosyl complex, related to the active site of NiFe hydrogenase

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Frank Osterloh, Wolfgang Saak, Detlev Haase and Siegfried Pohl

Abstract

[NiL] 1 (L = N,N′-diethyl-3,7-diazanonane-1,9-dithiolate) reacts with [Fe(CO)2(NO)2] 2 to afford [Ni(L)Fe(NO)2] 3, in which a NiII ion and a nitrosylated Fe-II centre are bridged via two µ-S atoms from the chelating ligand.

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