Control of interpenetrating copper(i) adamantoid networks: synthesis and structure of {[Cu(bpe)2]BF4}n

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Alexander J. Blake, Neil R. Champness, Simon S. M. Chung, Wan-Sheung Li and Martin Schröder


Abstract

Lengthening of linking bipyridyl ligands in interlocking copper(I)-heterocycle adamantoid arrays increases the volume of the adamantoid cages and consequently the number of observed interpenetrating networks: factors influencing the observed structures of these interpenetrating complexes are described in the context of the structure of {[Cu-(bpe)2]BF4}n [bpe = 1,2-trans-(4-pyridyl)ethene].


References

  1. G. R. Desiraju, in Crystal Engineering: Design of Organic Solids, Elsevier, Amsterdam, 1989 Search PubMed.
  2. The Crystal as a Supramolecular Entity, ed. G. R. Desiraju, Wiley, 1995 Search PubMed.
  3. G. R. Desiraju, Angew. Chem., Int. Ed. Engl., 1995, 34, 2311 CrossRef CAS.
  4. R. Robson, B. F. Abrahams, S. R. Batten, R. W. Gable, B. F. Hoskins and J. Liu, Supramolecular Architecture, ACS publications, 1992, ch. 19 Search PubMed.
  5. L. R. MacGillivary, S. Subramanian and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1994, 1325 RSC.
  6. L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, J. Chem. Soc., Chem. Commun., 1994, 2755 RSC.
  7. S. B. Copp, S. Subramanian and M. J. Zaworotko, J. Am. Chem. Soc., 1992, 114, 8719 CrossRef CAS; S. B. Copp, S. Subramanian and M. J. Zaworotko, J. Chem. Soc., Chem. Commun., 1993, 1078 RSC; S. B. Copp, K. T. Holman, J. O. S. Sangster, S. Subramanian and M. J. Zaworotko, J. Chem. Soc., Dalton Trans., 1995, 2233 RSC.
  8. D. Venkataraman, S. Lee, J. S. Moore, P. Zhang, K. A. Hirsch, G. B. Gardner, A. C. Covey and C. L. Prentice, Chem. Mater., 1996, 8, 2030 CrossRef CAS; B. F. Abrahams, S. R. Batten, H. Hamit, B. F. Hoskins and R. Robson, Angew. Chem., Int. Ed. Engl., 1966, 35, 1690 CrossRef; J. Black, N. R. Champness, W. Levason and G. Reid, Inorg. Chem., 1996, 35, 4432 CrossRef CAS; L. Carlucci, G. Ciani, D. M. Prosperio and A. Sironi, J. Am. Chem.. Soc., 1995, 117, 4562 CrossRef CAS; B. F. Hoskins and R. Robson, J. Am. Chem. Soc., 1990, 112, 1546 CrossRef CAS; O. M. Yaghi and H. Li, J. Am. Chem. Soc., 1995, 117, 10 401 CrossRef CAS; D. M. L. Goodgame, S. Menzer, A. M. Smith and D. J. Williams, Angew. Chem., Int. Ed. Engl., 1995, 34, 574 CrossRef CAS; P. C. M. Duncan, D. M. L. Goodgame, S. Menzer and D. J. Williams, Chem. Commun., 1996, 2127 RSC.
  9. O. Ermer, J. Am. Chem. Soc., 1988, 110, 3747 CrossRef CAS.
  10. D. B. Amabilino and J. F. Stoddart, Chem. Rev., 1995, 95, 2725 CrossRef CAS.
  11. B. F. Abrahams, S. R. Batten, H. Hamit, B. F. Hoskins and R. Robson, Chem. Commun., 1996, 1313 RSC.
  12. L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, Chem. Commun., 1996, 1393 RSC.
  13. K. A. Hirsch, D. Venkataraman, S. R. Wilson, J. S. Moore and S. Lee, J. Chem. Soc., Chem. Commun., 1995, 2199 RSC.
  14. SHELXS-96: G. M. Sheldrick, Universität Göttingen, 1996.
  15. SHELXL-96: G. M. Sheldrick, Universität Göttingen, 1996.
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