Ruthenium catalysed hydrogenation of dimethyl oxalate to ethylene glycol

(Note: The full text of this document is currently only available in the PDF Version )

Herman T. Teunissen and Cornelis J. Elsevier


Abstract

Dimethyl oxalate is efficiently hydrogenated to ethylene glycol under mild conditions [p(H2) 70 bar; 100 °C] using a ruthenium catalyst based on Ru(acac)3 and MeC(CH2PPh2)3.


References

  1. R. A. Grey, G. P. Pez and A. Wallo, J. Am. Chem. Soc., 1981, 103, 7536 CrossRef CAS .
  2. U. Matteoli, G. Menchi, M. Bianchi and F. Piacenti, J. Mol. Catal., 1988, 44, 347 CrossRef CAS .
  3. U. Matteoli, G. Menchi, M. Bianchi, F. Piacenti, S. Ianelli and M. Nardelli, J. Organomet. Chem., 1995, 498, 177 CrossRef CAS  and references cited therein.
  4. Y. Hara and K. Wada, Chem. Lett., 1991, 553 CAS .
  5. For the use of MeC(CH2PPh2)3 in catalysis, see C. Bianchini, A. Meli, M. Peruzzini, F. Vizza and F. Zanobini, Coord. Chem. Rev., 1992, 120, 193 Search PubMed .
Click here to see how this site uses Cookies. View our privacy policy here.