Synthesis and X-ray crystal structure of a novel neutral trinuclear copper(ii) hydridotris(3,5-dimethylpyrazolyl)borate complex with 1,1-azido bridges

(Note: The full text of this document is currently only available in the PDF Version )

Michael H. W. Lam, Yan-Yee Tang, Ka-Man Fung, Xiao-Zeng You and Wing-Tak Wong


Abstract

The X-ray crystal structure and magnetic properties of a neutral trinuclear 1,1-azido bridged copper(II) complex [LCu(µ-N3)2Cu(µ-N3)2CuL] 2 [L = hydridotris(3,5-dimethylpyrazolyl)borate], produced from the reaction between [Cu3L2]Cl 1 and an excess of trimethylsilyl azide, are reported.


References

  1. (a) R. Österberg, Coord. Chem. Rev., 1974, 12, 309 CrossRef CAS; (b) The Biochemistry of Copper, ed. J. Peisach and P. Aisen, W. E. Blumberg, Academic Press, New York, 1966 Search PubMed; (c) J. O. Allen, L. Yen and N. J. Farrier, J. Am. Chem. Soc., 1970, 92, 4475 CrossRef; (d) M. I. Bruce and A. P. P. Ostazewski, J. Chem. Soc., Dalton Trans., 1973, 2433 RSC; (e) M. I. Bruce, J. Organomet. Chem., 1972, 44, 209 CrossRef CAS; (f) C. S. Arcus, J. L. Wilkinson, C. Mealli, T. J. Marks and J. A. Ibers, J. Am. Chem. Soc., 1974, 96, 7564 CrossRef CAS; (g) C. S. Arcus, J. L. Wilkinson, C. Mealli, T. J. Marks and J. A. Ibers, J. Am. Chem. Soc., 1976, 98, 711 CrossRef CAS.
  2. M. P. Doyle, Chem. Rev., 1986, 86, 919 CrossRef CAS; G. Maas, Top. Curr. Chem., 1987, 137, 75 CAS; D. A. Evans, K. A. Woerpel, M. M. Hinman and M. M. Faul, J. Am. Chem. Soc., 1911, 113, 728; C. J. Tokar, P. B. Kettler and W. B. Tolmar, Organometallics, 1992, 11, 2737 CrossRef CAS; U. Leutenegger, G. Umbricht, C. Fahrni, P. V. Matt and A. Pfaltz, Tetrahedron, 1992, 48, 2143 CrossRef CAS; J. P. Pedro, M. Brookhart and J. L. Templeton, Organometallics, 1993, 12, 261 CrossRef CAS.
  3. R. Söderquist, Acta Crystallogr. Sect. B., 1968, 24, 450 CrossRef CAS.
  4. R. Vicente, A. Escuer, X. Solans and M. Font-Bardia, J. Chem. Soc., Dalton Trans., 1996, 1835 RSC.
  5. (a) J. Comarmond, P. Plumere, J.-M. Lehn, Y. Angus, R. Louis, R. Weiss, O. Kahn and I. Morgenstern-Badarau, J. Am. Chem. Soc., 1982, 104, 6330 CrossRef; (b) K. D. Karlin, J. C. Hayes, J. P. Hutchinson and J. Zubieta, J. Chem. Soc., Chem. Commun., 1983, 376 RSC; (c) O. Kahn, S. Sikorav, J. Gouterson, S. Jeannin and Y. Jeannin, Inorg. Chem., 1983, 22, 2877 CrossRef CAS; (d) K. D. Karlin, A. Farooq, J. C. Hayes, B. I. Cohen, T. M. Rowe, E. Sinn and J. Zubieta, Inorg. Chem., 1987, 26, 1271 CrossRef CAS; (e) R. Cortés, M. K. Urtiaga, L. Lezama, J. I. R. Larramendi, M. I. Arriortua and T. Rojo, J. Chem. Soc., Dalton Trans., 1993, 3685 RSC.
  6. J. S. Thompson, R. L. Harlow and J. F. Whitney, J. Am. Chem. Soc., 1983, 105, 3522 CrossRef CAS.
  7. C. J. O'Connor, Prog. Inorg. Chem., 1982, 29, 203 CAS.
Click here to see how this site uses Cookies. View our privacy policy here.