Epoxidation of unsaturated fatty esters over large-pore Ti-containing molecular sieves as catalysts: important role of the hydrophobic–hydrophilic properties of the molecular sieve

(Note: The full text of this document is currently only available in the PDF Version )

M. A. Camblor, A. Corma, P. Esteve, A. Martínez and S. Valencia


Abstract

Ti-β and Ti-MCM-41 catalysts are able to epoxidize methyl oleate using hydrogen peroxide or tert-butyl hydroperoxide as oxygen donors with high conversions and epoxide selectivities.


References

  1. H. Endres, H. Fischer, F. Loeffelholz, P. Wedl, K. Worchech, A. Hansen and G. Geismar, DE Pat., 4,117,034, 1991 Search PubMed.
  2. V. Shaefer, R. Kohler, A. Pauli and A. Fessenbecker, EP Pat., 557,839, 1992 Search PubMed.
  3. I. Scheuffsen and A. Meffert, DE Pat., 3,326,455, 1983 Search PubMed.
  4. J. Yanagida, T. Matsumoto and M. Nakayama, JP Pat., 04,134,001, 1990 Search PubMed.
  5. M. Niki and K. Otani, JP Pat., 02,206,613, 1989 Search PubMed.
  6. T. Kato, JP Pat., 62,99,348, 1985 Search PubMed.
  7. G. Diekelmann, K. Eckwert, L. Jeromin, E. Peukert and U. Steinberner, DE Pat., 3,320,219, 1983 Search PubMed.
  8. P. E. Sonnet, M. E. Laukin and G. P. McNeill, J. Am. Oil Chem. Soc., 1995, 72, 199 CAS.
  9. M. Quaglino, N. Bottazzini, C. Querci, M. Ricci and S. Cavalli, J. Am. Oil Chem. Soc., 1992, 69, 1248 CAS.
  10. E. Ucciani, A. Borfand, G. Rafaralahitsimba and G. Cecchi, Rev. Fr. Corps Gras, 1992, 39, 279 Search PubMed.
  11. M. C. Kuo and T. C. Chou, Can. J. Chem. Eng., 1990, 68, 831 Search PubMed.
  12. A. Debal, G. Rafaralahitsimba and E. Ucciani, Fat Sci. Technol., 1995, 95, 236 Search PubMed.
  13. U. Romano, A. Esposito, F. Maspero, C. Neri and C. Clerici, Stud. Surf. Sci. Catal., 1990, 55, 33.
  14. M. A. Camblor, A. Corma, A. Martínez and J. Pérez-Pariente, J. Chem. Soc., Chem. Commun., 1992, 589 RSC.
  15. A. Corma, M. T. Navarro and J. Pérez-Pariente, J. Chem. Soc., Chem. Commun., 1994, 147 RSC.
  16. A. Corma, M. A. Camblor, P. Esteve, A. Martínez and J. Pérez-Pariente, J. Catal., 1994, 145, 151 CrossRef CAS.
  17. T. Blasco, A. Corma, M. T. Navarro and J. Pérez-Pariente, J. Catal., 1995, 156, 65 CrossRef CAS.
  18. A. Corma, P. Esteve and A. Martínez, J. Catal., 1996, 161, 11 CrossRef CAS.
  19. G. Bellussi, A. Carati, M. G. Clerici, G. Maddinelli and R. Millini, J. Catal., 1992, 133, 220 CrossRef CAS.
  20. M. A. Camblor, M. Costantini, A. Corma, L. Gilbert, P. Esteve, A. Martínez and S. Valencia, Chem. Commun., 1996, 1339 RSC.
Click here to see how this site uses Cookies. View our privacy policy here.