View PDF Version
 
DOI: 10.1039/A700446J (Paper) Reference Section for: Chem. Commun., 1997, 631-632

Self-assembly of a three-dimensional network from two-dimensional layers via metallic spacers: the (3,4)-connected frame of [Ag3(hmt)2][ClO4]3·2H 2O (hmt = hexamethylenetetramine)

(Note: The full text of this document is currently only available in the PDF Version )

Lucia Carlucci, Gianfranco Ciani, Dorothea W. v. Gudenberg, Davide M. Proserpio and Angelo Sironi

Abstract

AgClO4 reacts with hexamethylenetetramine (hmt) in ethanol–CH2Cl2 in the ratio 1:1 to yield the two-dimensional polymer [Ag(hmt)] ClO4, consisting of hexagonal meshed layers, while a twofold excess of AgClO4 produces [Ag3- (hmt)2]ClO4]3·2H2O, in which AgI ions intercalate between the sheets of the two-dimensional polymer, joining them as spacers to give a three-dimensional (3,4)-connected open network of uncommon topological type.

References

  1. B. F. Hoskins and R. Robson, J. Am. Chem. Soc., 1990, 112, 1546 CrossRef CAS; R. Robson, B. F. Abrahams, S. R. Batten, R. W. Gable, B. F. Hoskins and J. Liu, Supramolecular Architecture, ACS publications, Washington, 1992, ch. 19 Search PubMed.
  2. C. L. Bowes and G. A. Ozin, Adv. Mater., 1996, 8, 13 CAS.
  3. S. R. Baten, B. F. Hoskins and R. Robson, Angew. Chem., Int. Ed. Engl., 1995, 34, 820 CrossRef; J. Am. Chem. Soc., 1995, 117, 5385 Search PubMed; B. F. Abrahams, S. R. Baten, H. Hamit, B. F. Hoskins and R. Robson, Chem. Commun., 1996, 1313 Search PubMed; B. F. Abrahams, S. R. Baten, H. Hamit, B. F. Hoskins and R. Robson, Angew. Chem., Int. Ed. Engl., 1996, 35, 1690 RSC.
  4. G. B. Gardner, D. Venkataraman, J. S. Moore and S. Lee, Science, 1995, 374, 792 CAS; D. Venkataraman, S. Lee, J. S. Moore, P. Zhang, K. A. Hirsch, G. B. Gardner, A. C. Covey and C. L. Prentice, Chem. Mater., 1996, 8, 2030 CrossRef CAS.
  5. B. F. Abrahams, S. J. Egan, B. F. Hoskins and R. Robson, Chem. Commun., 1996, 1099 RSC.
  6. G. R. Desiraju, Angew. Chem., Int. Ed. Engl., 1995, 34, 2311 CrossRef CAS.
  7. O. Ermer, J. Am. Chem. Soc., 1988, 110, 3747 CrossRef CAS.
  8. L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, J. Am. Chem. Soc., 1995, 117, 12 861 CrossRef CAS.
  9. A. Michelet, B. Voissat, P. Khodadad and N. Rodier, Acta Crystallogr., Sect. B, 1981, 37, 2171 CrossRef.
  10. A. F. Wells, Further Studies of Three-dimensional Nets, ACA Monograph No. 8, 1979 Search PubMed.
  11. K. Schubert, E. Doerre and E. Guenzel, Naturwissenschaften, 1954, 41, 448 CrossRef CAS; R. Walther and H. J. Deiseroth, Z. Krystallogr., 1995, 210, 360 CAS.
Click here to see how this site uses Cookies. View our privacy policy here.