Fe(η5-C5H5)+ initiated construction of hexaruthenium–polypyridine complexes

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Valérie Marvaud and Didier Astruc


Abstract

Aromatic stars containing hexa-pyridine, -bipyridine and -terpyridine branches are synthesised with or without the central Fe(η5-C5H5)+ group and coordinated to ru-thenium(II) polypyridine moities to construct hexa- and hepta-nuclear hexa-bipyiridine and -terpyridine complexes.


References

  1. J.-M. Lehn, Supramolecular Chemistry, VCH, Weinheim, 1995 Search PubMed; V. Balzani and F. Scandola, Supramolecular Photochemistry, Ellis Horwood, New York, 1991 Search PubMed; V. Balzani, Supramolecular Photochemistry, Reidel, Dordrecht, 1987, p. 35 Search PubMed; F. Vögtle, Supramolecular Chemistry, 2nd edn., Wiley, Chichester Search PubMed.
  2. K. Wärnmark, O. Heyke, J. A. Thomas and J.-M. Lehn, Chem. Commun., 1996, 2603 RSC; C. Fouquey, J.-M. Lehn and A.-M. Levelut, Adv. Mater., 1990, 2, 254 CrossRef CAS; T. Gulik-Krzywicki, C. Fouquey and J.-M. Lehn, Proc. Natl. Acad. Sci. USA, 1993, 90, 163; R. Krämer, J.-M. Lehn and A. Marquis-Rigault, Proc. Natl. Acad. Sci. USA, 1993, 90, 53934.
  3. E. C. Constable, in Comprehensive Supramolecular Chemistry, ed. J.-P. Sauvage and M.-W. Hosseini, Pergamon, Oxford, 1996, vol. 9, ch. 6, pp. 213–252 Search PubMed; C. Piguet, G. Hopfgartner, B. Bocquet, O. Schaad and A. F. Williams, J. Am. Chem. Soc., 1994, 116, 9092 Search PubMed; C. Piguet, J. C. G. Bunzli, G. Bernardinelli, G. Hopfgartner and A. F. Williams, J. Chem. Soc., Chem. Commun., 1995, 491 CrossRef CAS; U. Velten and M. Rehahn, Chem. Commun., 1996, 2639 RSC.
  4. S. Serroni, G. Denti, S. Campagna, A. Juris, M. Ciano and V. Balzani, Angew. Chem., 1992, 104, 1540 CAS; Angew. Chem., Int. Ed. Engl., 1992, 31, 1493 Search PubMed; S. Denti, S. Campagna, S. Serroni, M. Ciano and V. Balzani, J. Am. Chem. Soc., 1992, 114, 2944 Search PubMed; S. Campagna, G. Denti, S. Serroni, M. Ciano, A. Juris and V. Balzani, Inorg. Chem., 1992, 31, 2982 CrossRef CAS; V. Balzani, A. Credi and F. Scandola, in Transition Metals in Supramolecular Chemistry, ed. L. Fabbrizzi and A. Poggi, Kluwer, Dordrecht, 1994, p. 1 CrossRef CAS.
  5. G. R. Newkome, F. Cardullo, E. C. Constable, C. N. Moorefield and A. M. W. Cargill Thomson, J. Chem. Soc., Chem. Commun., 1993, 925 RSC; E. C. Constable and P. Harverson, Chem. Commun., 1996, 33 RSC; E. C. Constable, P. Harverson and M. Oberholzer, Chem. Commun., 1996, 1821 RSC.
  6. C. Moucheron, A. Kirsch-De Mesmaeker, A. Dupont-Gervais, E. Leize and A. Van Dorsselaer, J. Am. Chem. Soc., 1996, 118, 12834 CrossRef CAS.
  7. V. Balzani, A. Juris, M. Venturi, S. Campagna and S. Serroni, Chem. Rev., 1996, 96, 759 CrossRef CAS; J.-P. Sauvage, S. Guillerez, C. Coudret, V. Balzani, F. Barigeletti, L. De Cola and L. Flamigni, Chem. Rev., 1994, 94, 993 CrossRef CAS; A. Juris, V. Balzani, F. Barigeletti, S. Campagna, P. Belser and A. Von Zelewski, Coord. Chem. Rev., 1988, 84, 85 CrossRef CAS; P. J. Steel, Coord. Chem. Rev., 1990, 106, 227 CrossRef CAS.
  8. D. Astruc, Electron Transfer and Radical Processes in Transition-Metal Chemistry, VCH, New York, 1995, ch. 2 Search PubMed; D. Astruc, in Mechanisms and Processes in Molecular Chemistry, ed. D. Astruc, Gauthier-Villard, Paris Search PubMed; New J. Chem., 1992, 16, 305 Search PubMed.
  9. (a) J.-L. Fillaut, J. Linares and D. Astruc, Angew. Chem., 1994, 106, 2540 CAS; Angew. Chem., Int. Ed. Engl., 1994, 33, 2460 Search PubMed; (b) F. Moulines and D. Astruc, Angew. Chem., 1988, 100, 1394 CAS; Angew. Chem., Int. Ed. Engl., 1988, 27, 1347 Search PubMed.
  10. C. A. Fyfe, in The Chemistry of the Hydroxyl group, Part 1, ed. S. Patai, Wiley, New York, 1971, pp. 83–124 Search PubMed.
  11. (a) R. A. Jones, B. d. Roney, W. H. F. Sasse and K. O. Wade, J. Chem. Soc. B, 1967, 106 RSC; (b) B. P. Sullivan, J. M. Calvert and T. Meter, Inorg. Chem., 1980, 19, 1404 CrossRef.
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