View PDF Version
 
DOI: 10.1039/A700360I (Paper) Reference Section for: Chem. Commun., 1997, 777-778

Activation of CO2 by laser-ablated group 6 metal atoms

(Note: The full text of this document is currently only available in the PDF Version )

Philip F. Souter and Lester Andrews

Abstract

The primary reaction products of laser-ablated group 6 atoms with CO2 prove to be the insertion products OMCO and O2M(CO)2 (M = Cr, Mo, W) which are isolated in argon matrices and identified by the effects of isotopic substitution on their IR spectra.

References

  1. J. A. Ibers, Chem. Soc. Rev., 1982, 11, 57 RSC.
  2. C. Creutz, in Electrochemical and Electrocatalytic Reactions of Carbon Dioxide, ed. B. P. Sullivan, K. Krist and H. E. Guard, Elsevier, Amsterdam, 1993, ch. 2 Search PubMed.
  3. M. Arreseta, E. Quarntana and I. Tommasi, New J. Chem., 1994, 18, 133 Search PubMed.
  4. D. H. Gibson, Chem. Rev., 1996, 96, 2063 CrossRef CAS.
  5. M. M. Halmann, Chemical Fixation of Carbon Dioxide. Methods for Recycling CO2 into Useful Products, CRC Press, Boca Raton, FL, 1993 Search PubMed.
  6. See for example, A. R. Cutler, P. K. Hanna and J. C. Vites, Chem. Rev., 1988, 88, 1363 Search PubMed.
  7. Z. H. Kafafi, R. H. Hauge, W. E. Billups and J. L. Margrave, J. Am. Chem. Soc., 1983, 105, 3886 CrossRef CAS.
  8. Z. H. Kafafi, R. H. Hauge, W. E. Billups and J. L. Margrave, Inorg. Chem., 1984, 23, 177 CrossRef CAS.
  9. A. M. LeQuere, C. Xu and L. Manceron, J. Phys. Chem., 1991, 95, 3031 CrossRef CAS.
  10. J. Mascetti and M. Tranquille, J. Phys. Chem., 1988, 92, 2177 CrossRef CAS.
  11. G. H. Yeung, Mol. Phys., 1988, 65, 669.
  12. T. R. Burkholder and L. Andrews, J. Phys. Chem., 1993, 97, 3500 CrossRef CAS.
  13. T. J. Tague, Jr., L. Andrews and R. D. Hunt, J. Phys. Chem., 1993, 97, 10 920 CrossRef.
  14. G. V. Chertihin and L. Andrews, J. Am. Chem. Soc., 1995, 117, 1595 CrossRef CAS.
  15. L. Andrews and T. J. Tague, Jr., J. Am. Chem. Soc., 1994, 116, 6856 CrossRef CAS.
  16. T. R. Burkholder and L. Andrews, J. Chem. Phys., 1991, 95, 8697 CrossRef CAS.
  17. G. V. Chertihin, W. D. Bare and L. Andrews, unpublished work.
  18. M. Poliakoff, K. P. Smith, J. J. Turner and A. J. Wilkinson, J. Chem. Soc. Dalton Trans., 1982, 651 RSC.
  19. J. A. Crayston, M. J. Almond, A. J. Downs, M. Poliakoff and J. J. Turner, Inorg. Chem., 1984, 23, 3051 CrossRef CAS.
  20. M. J. Almond, J. A. Crayston, A. J. Downs, M. Poliakoff and J. J. Turner, Inorg. Chem., 1986, 25, 19 CrossRef CAS.
  21. M. J. Almond and A. J. Downs, J. Chem. Soc., Dalton Trans., 1988, 809 RSC.
  22. T. C. Devor and J. L. Gole, Chem. Phys., 1989, 133, 95 CrossRef.
  23. J. K. Bates and D. M. Gruen, J. Mol. Spectrosc., 1979, 78, 284 CrossRef CAS.
  24. D. W. Green and K. M. Ervin, J. Mol. Spectrosc., 1981, 89, 145 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.