Modification of MCM-41 via ring opening of a strained [1]ferrocenophane

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Stephen O’Brien, Jonathan Tudor, Stephen Barlow, Mark J. Drewitt, Stephen J. Heyes and Dermot O’Hare


Abstract

The walls of the mesoporous silicate MCM-41 can be functionalised with ferrocenyl end groups by reaction with an alkane solution of (1,1′-ferrocenediyl)dimethylsilane; the product is studied by solid-state NMR and EXAFS spectroscopies.


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