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DOI: 10.1039/A700089H (Paper) Reference Section for: Chem. Commun., 1997, 847-848

Synthesis, derivatization, and structural characterization of [Mn(CNC6H3Me2-2,6)5] -, a five-coordinate isonitrilate complex containing Mn-I

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Tracy L. Utz, Patricia A. Leach, Steven J. Geib and N. John Cooper

Abstract

Naphthalenide reduction of [Mn(CNC6H3Me2-2,6)5Cl] forms solutions of trigonal-bipyramidal [Mn(CNC6H3Me2-2,6)5] -, as established by an X-ray diffraction study of a [K(18-C-6)(dme)]+ salt and derivatization with SnClPh3 to give [Mn(CNC6H3Me2-2,6)5(SnPh 3)].

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