DOI: 10.1039/A700019G
(Paper)
Reference Section for: Chem. Commun., 1997, 745-746
Large negative cubic hyperpolarizability for the spin-crossover compound cis-bis(thiocyanato)bis[N-(2-pyridylmethylene)aminobiph enyl]iron(ii)
(Note: The full text of this document is currently only available in the PDF Version )
Jean-François Létard, Sébastien Montant, Philippe Guionneau, Partick Martin, Annie Le Calvez, Eric Freysz, Daniel Chasseau, René Lapouyade and Olivier Kahn
Abstract
The first example of a spin-crossover iron(II) compound with a large negative third-order polarizability, associated with an instantaneous electronic response, is reported; magnetic measurements show that this compound, cis-bis(thio-cyanato)bis[N-(2-pyridylmethylene)aminobip henyl]iron(II), characterized by X-ray structural data is in the high-spin form at room temperature.
References
- D. S. Chemla and J. Zyss, Nonlinear Optical Properties of Organic Molecules and Crystals, Academic, Orlando, FL, 1987, vol. 1 and 2 Search PubMed.
- D. R. Kanis, M. A. Ratner and T. J. Marks, Chem. Rev., 1994, 94, 195 CrossRef CAS.
- C. W. Dirk, W. C. Herndon, F. Cervantes-Lee, H. Selnau, S. Martinez, P. Kalamegham, A. Tan, G. Campos, M. Velez, J. Zyss, I. Ledoux and L.-T. Cheng, J. Am. Chem. Soc., 1995, 117, 2214 CrossRef CAS.
- D. W. Samuel, I. Ledoux, C. Dhenaut, J. Zyss, H. H. Fox, R. R. Schrock and R. J. Silbey, Science, 1994, 265, 1070 CAS.
- H. S. Nalwa, Adv. Mater., 1993, 5, 341 CrossRef.
- For recent general reviews of NLO materials involving organometallic and coordination complexes, see: H. S. Nalwa, Appl. Organomet. Chem., 1991, 5, 349 Search PubMed; N. J. Long, Angew. Chem., Int. Ed. Engl., 1995, 34, 21 CrossRef CAS.
- I. R. Whittall, M. G. Humphrey, M. Samoc, J. Swiatkiewicz and B. Luther-Davies, Organometallics, 1995, 14, 5493 CrossRef CAS.
- M. A. Díaz-García, I. Ledoux, F. Fernández-Lázaro, A. Sastre, T. Torres, F. Agulló-López and J. Zyss, J. Phys. Chem., 1994, 98, 4495 CrossRef CAS; M. A. Díaz-García, I. Ledoux, F. Fernández-Lázaro, A. Sastre, T. Torres, F. Agulló-Lopez and J. Zyss, Nonlinear Opt., 1995, 10, 101 Search PubMed.
- M. A. Díaz-García, I. Ledoux, J. A. Duro, T. Torres, F. Agulló-López and J. Zyss, J. Phys. Chem., 1994, 98, 8761 CrossRef CAS.
- P. Gütlich, A. Hauser and H. Spiering, Angew. Chem., Int. Ed. Engl., 1994, 33, 2024 CrossRef; O. Kahn, J. Kröber and C. Jay, Adv. Mater., 1992, 4, 718 CrossRef CAS.
- B. Gallois, J.-A. Real, C. Hauw and J. Zarembowitch, Inorg. Chem., 1990, 29, 1152 CrossRef CAS.