DOI: 10.1039/A608178I
(Paper)
Reference Section for: Chem. Commun., 1997, 717-718
Structural interconversion facilitated by a bifunctional ligand: a covalently linked 2D CuII sheet [Cu(3-pyOH)2(O2CCF3)2] n and a hydrogen-bond linked 2D CuII sheet [Cu(3-pyOH2)(O2CCF3)2(thf) 2]n
(Note: The full text of this document is currently only available in the PDF Version )
Satoshi Kawata, Steven R. Breeze, Suning Wang, John E. Greedan and N. P. Raju
Abstract
A covalently linked 2D CuII compound, [Cu(O2CCF3)2(3-pyOH)2] n 1 (3-pyOH = 3-hydroxypyridine), when dissolved in thf, undergoes conversion to a hydrogen-bond linked 2D CuII compound, [Cu(O2CCF3)2(3-pyOH)2(thf) 2] 2, which upon heating or standing at 23 °C for a few hours is converted back to compound 1 by losing the coordinated thf molecule; weak ferromagnetic interactions between CuII centres dominate in both compounds.
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