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DOI: 10.1039/A608173H (Paper) Reference Section for: Chem. Commun., 1997, 387-388

Template synthesis of [Cr(en)3][Te6]: a novel polytelluride with a framework structure, whose cavities are filled with a [Cr(en)3]3+ template

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Christian Reisner and Wolfgang Tremel

Abstract

[Cr(en)3][Te6] (en = ethylenediamine) is obtained by a template synthesis under solvothermal conditions from Cr(CO)6 and BaTe4; its crystal structure contains a polymeric Te63- framework whose pores contain the Cr(en)33+ template; [Cr(en)3][Te6] is the first chalcogenide with a porous three-dimensional framework structure.

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