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DOI: 10.1039/A608131B (Paper) Reference Section for: Chem. Commun., 1997, 405-406

Association of two incomplete cubane WS3Cu3 clusters in the crystal structures of [PPh4]2[{(C5Me5)WS3 }2Cu6(NCS)6] and [PPh4]2[{(C5Me5)WS3 }2Cu6Br6]

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Jianping Lang, Hiroyuki Kawaguchi, Shiho Ohnishi and Kazuyuki Tatsumi

Abstract

Two double cubane-like clusters, [PPh4]2[{(C5Me5)- WS3}2Cu6(NCS)6] 1 and [PPh4]2[{(C5Me5)WS3 }2Cu6Br6] 2, are self-assembled by the reactions of [PPh4][(C5Me5)WS3] with CuNCS and CuBr in acetonitrile, respectively, the crystal structures of which consist of two WS3Cu3 incomplete cubes linked by NCS and Br bridges.

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