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DOI: 10.1039/A608115K (Paper) Reference Section for: Chem. Commun., 1997, 1069-1070

Mechanistic study on meso-hydroxyoctaethylporphyrin formation from an FeIII(oep)–H2O2 complex

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Kunihiko Tajima, Kohji Tada, Masato Shigematsu, Kenji Kanaori, Nagao Azuma and Keisuke Makino

Abstract

The benzoyl ester of an iron(III) meso-hydroxyoctaethylporphyrin complex, containing 18O derived from molecular oxygen, is isolated from the reaction solution of the complex [FeIII(oep)(OOH)(OH)]- which is prepared by reduction of [FeII(oep)(py)(18O2)] with sodium ascorbate.

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