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DOI: 10.1039/A607904K (Paper) Reference Section for: Chem. Commun., 1997, 913-914

Oxidative addition of a C–Se bond to a PtII centre: contrasting reactions of [MCl2(PhCN)2] (M = Pd, Pt) with cyclohepteno-1,4-diselenin

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C. Matthew Bates, Pawan K. Khanna, Christopher P. Morley and Massimo Di Vaira

Abstract

The reaction of cyclohepteno-1,4-diselenin 1 with [PtCl2(PhCN)2] proceeds via unprecedented oxidative addition of a C–Se bond to yield a platinum(IV) product, whose novel dimeric structure has been determined by X-ray crystallography; by contrast, 1 reacts with [PdCl2(PhCN)2] to form trans-[PdCl2L2] (L = 1).

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