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DOI: 10.1039/A607833H (Paper) Reference Section for: Chem. Commun., 1997, 459-460

First example of thiolate-bridged square-pyramidal and octahedral nickel(ii) ions: [Ni2(LSO)(NCS)2(dmf)]

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Sally Brooker and Paul D. Croucher

Abstract

A structure determination reveals that [Ni2(LSO)- (NCS)2(dmf)] 2 is one of the best structural models to date for the active site of [Ni,Fe] hydrogenases: it also contains the first example of a high-spin thiolate-bound square-pyramidal nickel(II) ion.

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