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DOI: 10.1039/A607827C (Paper) Reference Section for: Chem. Commun., 1997, 481-482

The first structurally authenticated zerovalent heteroarene complex of a lanthanide; synthesis and X-ray structure of bis(2,4,6-tri-tert-butyl- phosphorin)holmium(O)

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Polly L. Arnold, F. Geoffrey N. Cloke and Peter B. Hitchcock

Abstract

Holmium vapour reacts with 2,4,6-tri-tert-butylphosphorin to afford the zerovalent [Ho(η-PC5H2But3-2,4,6) 2], the first structurally characterised complex of this class.

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