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DOI: 10.1039/A607764A (Paper) Reference Section for: Chem. Commun., 1997, 339-340

Diversity of linking modes by N,N′-p-phenylenedimethylenebis(pyridin-4 -one) [p-XBP4] in the novel ‘linked lantern’ framework complex {[Nd2(p-XBP4)6(H2O)4 ](p-XBP4)(H2O)3(ClO4) 6}n

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David M. L. Goodgame, Stephan Menzer, Amanda M. Smith and David J. Williams

Abstract

The title compound has a complex framework structure in which pairs of Nd atoms are linked by four p-XBP4 ligands to form ‘lanterns’ which are further connected by interwoven Nd–(p-XBP4)–Nd bridges, and yet again by non-coordinated p-XBP4 molecules hydrogen bonded to aqua ligands on the Nd centres.

References

  1. An extensive and thorough overview is provided by: Comprehensive Supramolecular Chemistry, ed. J. L. Atwood, J. E. D. Davies, D. D. MacNicol and F. Vögtle, Elsevier Science, 1996 Search PubMed.
  2. See e.g.: M. Fujita, ch. 7 of vol. 9 of ref. 1.
  3. D. M. L. Goodgame, S. Menzer, A. M. Smith and D. J. Williams, J. Chem. Soc., Chem. Commun., 1995, 1975 RSC and references therein.
  4. D. M. L. Goodgame, S. Menzer, A. M. Smith and D. J. Williams, Angew. Chem., 1995, 107, 605; Angew. Chem., Int. Ed. Engl., 1995, 34, 574 Search PubMed.
  5. A. M. Smith, PhD Thesis, London University, 1995.
  6. G. M. Sheldrick, SHELXTL version 5.03, University of Göttingen, 1995.
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