DOI: 10.1039/A607700E
(Paper)
Reference Section for: Chem. Commun., 1997, 557-558
Synergistic oxidation of cyclohexane and hydrogen sulfide under Gif conditions
(Note: The full text of this document is currently only available in the PDF Version )
Derek H. R. Barton, Tingsheng Li and John MacKinnon
Abstract
Saturated hydrocarbons and hydrogen sulfide can be synergistically oxidised by oxygen (or air) to give efficiently ketones (and the corresponding alcohols) and sulfur in the presence of a Gif catalyst based on FeII, picolinic acid and 4-tert-butylpyridine with acetonitrile as solvent at room temperature and nearly neutral pH.
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