DOI: 10.1039/A607355G
(Paper)
Reference Section for: Chem. Commun., 1997, 653-654
Synthesis, structural characterisation and preliminary magnetic studies of a tetraicosanuclear cobalt coordination complex
(Note: The full text of this document is currently only available in the PDF Version )
Euan K. Brechin, Steven G. Harris, Andrew Harrison, Simon Parsons, A. Gavin Whittaker and Richard E. P. Winpenny
Abstract
The highest nuclearity complex containing cobalt consists of cubic-close packed planes of hydroxide, methoxide or chloride anions, bridging cobalt(II) centres; preliminary magnetic studies indicate a high-spin ground state and the possibility of superparamagnetic behaviour.
References
- A. Müller, K. Krickemeyer, J. Meyer, H. Bögge, F. Peters, W. Plass, E. Diemann, S. Dillinger, F. Nonenbruch, M. Randerath and C. Menke, Angew. Chem., Int. Ed. Engl., 1995, 34, 2122 CrossRef.
- H. Krautscheid, D. Fenske, G. Baum and M. Semmelmann, Angew. Chem., Int. Ed. Engl., 1993, 32, 1303 CrossRef.
- J.-F. You, G. C. Papafethymiou and R. C. Holm, J. Am. Chem. Soc., 1992, 114, 2697 CrossRef CAS.
- A. K. Powell, S. L. Heath, D. Gatteschi, L. Pardi, R. Sessoli, G. Spina, F. Del Giallo and F. Pieralli, J. Am. Chem. Soc., 1995, 117, 2491 CrossRef CAS.
- S. Parsons, G. A. Solan and R. E. P. Winpenny, J. Chem. Soc., Chem. Commun., 1995, 1987 RSC.
- G. M. Sheldrick, Acta Crystallogr., Sect. A, 1990, 46, 467 CrossRef.
- G. M. Sheldrick, SHELXL-93, University of Göttingen, 1993.
- P. van der Sluis and A. L. Spek, Acta Crystallogr., Sect. A, 1990, 46, 194 CrossRef.
- L. J. Pearce, C. K. Prout and D. J. Watkin, CAMERON: a program for graphical representation of structural data, Chemical Crystallography Laboratory, University of Oxford, 1994.
- J. P. Chen, C. M. Sorensen, K. J. Klabunder and G. C. Hadjipanayis, J. Appl. Phys., 1994, 78, 6318.
- R. L. Sessoli, H.-L. Tsai, A. R. Schake, S. Wang, J. B. Vincent, K. Folting, D. Gatteschi, G. Christou and D. N. Hendrickson, J. Am. Chem. Soc., 1993, 115, 1804 CrossRef CAS.