Novel molecular receptors capable of forming Cu2–O2 complexes. Effect of preorganization on O2 binding

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Robertus J. M. Klein Gebbink, Constantinus F. Martens, Martinus C. Feiters, Kenneth D. Karlin and Roeland J. M. Nolte


Abstract

Novel biomimetic copper(I) receptors react with O2 to form metastable O2 complexes and the rate of these reactions depends on the preorganization of the ligands.


References

  1. For selected reviews see: (a) Z. Tyeklár and K. D. Karlin, Acc. Chem. Res., 1989, 22, 241 CrossRef CAS; (b) T. N. Sorrell, Tetrahedron, 1989, 45, 3 CrossRef; (c) K. D. Karlin, Z. Tyeklár and A. D. Zuberbühler, in Bioinorganic Catalysis, ed. J. Reedijk, Marcel Dekker Inc., New York, 1993, pp. 261–315 Search PubMed; (d) N. Kitajima and Y. Moro-oka, Chem. Rev., 1994, 94, 737 CrossRef CAS; (e) S. Fox and K. D. Karlin, Dioxygen Reactivity in Copper Proteins and Complexes, in Reactive Oxygen in Biochemistry, ed. J. S. Valentine, C. S. Foote, A. Greenberg and J. F. Liebman, Blackie Academic & Professional, Chapman & Hall, Glasgow, 1995, pp. 188–231 Search PubMed.
  2. Bioinorganic Chemistry of Copper, ed. K. D. Karlin and Z. Tyeklár, Chapman & Hall, New York, 1993 Search PubMed.
  3. N. J. Blackburn, R. W. Strange, A. Farooq, M. S. Haka and K. D. Karlin, J. Am. Chem. Soc., 1988, 110, 4263 CrossRef CAS; N. Kitajima, K. Fujisawa and Y. Moro-oka, J. Am. Chem. Soc., 1989, 111, 8976 CrossRef; N. Kitajima, K. Fujisawa, C. Fujimoto, Y. Moro-oka, S. Hashimoto, T. Kitagawa, K. Toriumu, K. Tatsumi and A. Nakamura, J. Am. Chem. Soc., 1992, 114, 1277 CrossRef CAS; N. Kitajima and Y. Moro-oka, J. Chem. Soc., Dalton Trans., 1993, 2665 RSC.
  4. K. A. Magnus, H. Ton-That and J. E. Carpenter, Chem. Rev., 1994, 94, 727 CrossRef CAS.
  5. (a) K. D. Karlin, J. C. Hayes, Y. Gultneh, R. W. Cruse, J. W. McKown, J. P. Hutchinson and J. Zubieta, J. Am. Chem. Soc., 1984, 106, 2121 CrossRef CAS; (b) K. D. Karlin, B. I. Cohen, R. R. Jacobson and J. Zubieta, J. Am. Chem. Soc., 1987, 107, 6194 CrossRef; (c) I. Sanyal, M. Mahroof-Tahir, M. S. Nasir, P. Ghosh, B. I. Cohen, Y. Gultneh, R. W. Cruse, A. Farooq, K. D. Karlin, S. Liu and J. Zubieta, Inorg. Chem., 1992, 31, 4322 CrossRef CAS; (d) M. S. Nasir, B. I. Cohen and K. D. Karlin, J. Am. Chem. Soc., 1992, 114, 2482 CrossRef CAS; (e) L. Casella, M. Gulloti, G. Pallanza and L. Rigoni, J. Am. Chem. Soc., 1988, 100, 4221 CrossRef; (f) M. Réglier, C. Joraud and B. Waegell, J. Chem. Soc., Chem. Commun., 1990, 1752 RSC; (g) O. J. Gelling, A. Meetsma and B. L. Feringa, Inorg. Chem., 1990, 29, 2816 CrossRef CAS; (h) R. Menif, A. E. Martell, P. J. Squattrito and A. Clearfield, Inorg. Chem., 1990, 29, 4723 CrossRef CAS; (i) S. Mahaparta, J. A. Halfen, E. C. Wilkinson, L. Que Jr. and W. B. Tolman, J. Am. Chem. Soc., 1994, 116, 9785 CrossRef.
  6. C. F. Martens, R. J. M. Klein Gebbink, M. C. Feiters, H. Kooijman, W. J. J. Smeets, A. L. Spek and R. J. M. Nolte, Inorg. Chem., 1994, 33, 5541 CrossRef CAS.
  7. J. W. H. Smeets, R. P. Sijbesma, L. van Dalen, A. L. Spek, W. J. J. Smeets and R. J. M. Nolte, J. Org. Chem., 1989, 54, 3710 CrossRef CAS.
  8. K. I. Miller, E. Schabtach and K. E. van Holde, Proc. Natl. Acad. Sci. USA, 1990, 87, 1496 CAS.
  9. (a) E. I. Solomon, in Copper Coordination Chemistry: Biochemical and Inorganic Perspectives, ed. K. D. Karlin and J. Zubieta, Adenine Press, Guilderland, New York, 1983, pp. 1–22 Search PubMed; (b) N. C. Eickman, R. S. Himmelwright and E. I. Solomon, Proc. Natl. Acad. Sci. USA, 1979, 76, 2094 CAS.
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