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DOI: 10.1039/A607124D (Paper) Reference Section for: Chem. Commun., 1997, 181-182

Generation, entrapment and reactivity of long-lived organic carbocations and radical cations within a supramolecular assembly: Ca Y zeolite

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K. Pitchumani, P. H. Lakshminarasimhan, Nicolette Prevost, D. R. Corbin and V. Ramamurthy

Abstract

Diarylethenes spontaneously form the corresponding radical cations and carbocations upon inclusion within activated Ca Y zeolite; oxygen plays an important role in the generation of the radical cations.

References

  1. H. van Bekkum, E. M. Flanigen and J. C. Jansen, Introduction to Zeolite Science and Practice, Elsevier, Amsterdam, 1991 Search PubMed.
  2. (a) D. N. Stamires and J. Turkevich, J. Am. Chem. Soc., 1964, 86, 749 CrossRef CAS; (b) F. R. Chen and J. J. Fripiat, J. Phys. Chem., 1992, 96, 819 CrossRef CAS; (c) X. Liu, K. K. Iu, J. K. Thomas, H. He and J. Klinowski, J. Am. Chem. Soc., 1994, 116, 11811 CrossRef CAS; (d) A. Corma, V. Fornes, H. Garcia, V. Marti and M. A. Miranda, Chem. Mater., 1995, 7, 2136 CrossRef CAS.
  3. R. A. McClelland, V. M. Kanagasabapathy and S. Steenken, J. Am. Chem. Soc., 1988, 110, 6913 CrossRef CAS.
  4. H. P. Leftin and W. K. Hall, J. Phys. Chem., 1960, 64, 382 CAS; H. P. Leftin and W. K. Hall, J. Phys. Chem., 1962, 66, 1457 CAS.
  5. G. Turner, M. G. Bakker and V. Ramamurthy, unpublished work.
  6. J. W. Ward, in Zeolite Chemistry and Catalysis, ed. J. A. Rabo, American Chemical Society, Washington, DC, 1976, p. 118 Search PubMed; M. L. Poutsma, in Zeolite Chemistry and Catalysis, ed. J. A. Rabo, American Chemical Society, Washington, DC, 1976, p. 437 Search PubMed; P. E. Eberly, J. Phys. Chem., 1968, 72, 1042 Search PubMed; H. Hattori and T. Shiba, J. Catal, 1968, 12, 111 Search PubMed; J. W. Ward, J. Phys. Chem., 1968, 72, 4211 CrossRef CAS; J. Catal, 1968, 10, 34 CrossRef CAS; J. B. Uytterhoeven, R. Schoonheydt, B. V. Liengme and W. K. Hall, J. Catal., 1969, 13, 425 CrossRef CAS; J. W. Ward, J. Catal., 1969, 14, 365 CrossRef CAS; M. L. Costenoble, W. J. Mortier and J. B. Uytterhoeven, J. Chem. Soc., Faraday Trans., 1, 1977, 73, 466; 477 Search PubMed.
  7. For a recent publication, see: H. Sun, F. Blatter and H. Frei, J. Am. Chem. Soc., 1996, 118, 6873 Search PubMed.
  8. K. Gollnick, A. Schnatterer and G. Utschick, J. Org. Chem., 1993, 58, 6049 CrossRef CAS.
  9. K. B. Yoon and J. K. Kochi, J. Am. Chem. Soc., 1988, 110, 6586 CrossRef CAS.
  10. S. L. Mattes and S. Farid, J. Am. Chem. Soc., 1986, 108, 7356 CrossRef CAS; R. A. Neunteufel and D. R. Arnold, J. Am. Chem. Soc., 1973, 95, 4080 CrossRef CAS.
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