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DOI: 10.1039/A606962B (Paper) Reference Section for: Chem. Commun., 1997, 67-68

[Fe3Cu(SPri)6Cl3] 2-: a novel mixed-metal thiolate complex with a ‘truncated’ adamantane-like structure

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Hans-Oscar Stephan, Gerald Henkel and Mercouri G. Kanatzidis

Abstract

Reaction of [Fe2(SPri)6]2- with FeCl2 and CuCl in a 1:1:1 molar ratio in hot tetrahydrofuran gives the complex anion [Fe3Cu(SPri)6Cl3]2 - which contains a Fe3Cu pyramidal core; the structure, magnetic properties and the solution 1H NMR spectrum are reported.

References

  1. B. Krebs and G. Henkel, Angew. Chem., 1991, 103, 785 CAS; Angew. Chem., Int. Ed. Engl., 1991, 30, 769 Search PubMed.
  2. I. Dance and K. Fisher, Prog. Inorg. Chem., 1994, 41, 637 CAS.
  3. G. Henkel, B. Krebs, P. Betz, H. Fietz and K. Saatkamp, Angew. Chem., 1988, 100, 1375; Angew. Chem., Int. Ed. Engl., 1988, 27, 1326 Search PubMed.
  4. W. Hirpo, S. Dhingra and M. G. Kanatzidis, J. Chem. Soc., Chem. Commun., 1992, 557 RSC.
  5. M. Brewer, J. Lee and J. G. Brennan, Inorg. Chem., 1995, 34, 5919 CrossRef CAS.
  6. W. Hirpo, S. Dhingra, A. C. Sutorik and M. G. Kanatzidis, J. Am. Chem. Soc., 1993, 115, 1597 CrossRef CAS.
  7. H.-O. Stephan and G. Henkel, Polyhedron, 1996, 15, 501 CrossRef CAS.
  8. H.-O. Stephan, M. G. Kanatzidis and G. Henkel, Angew. Chem., Int. Ed. Engl., 1996, 35, 2135 CrossRef CAS.
  9. For example: (a) D. Swenson, N. C. Baenziger and D. Coucouvanis, J. Am. Chem. Soc., 1978, 100, 1932 CrossRef CAS; (b) K. S. Hagen and R. H. Holm, Inorg. Chem., 1984, 23, 418 CrossRef CAS; (c) G. Henkel and C. Chen, Inorg. Chem., 1993, 32, 1064 CrossRef CAS.
  10. See, for example: D. Coucouvanis, C. N. Murphy and S. K. Konodia, Inorg. Chem., 1980, 19, 2993 Search PubMed; M. Baumgartner, H. Schmalle and E. Dubler, Polyhedron, 1990, 9, 1155 CrossRef CAS; I. G. Dance and J. C. Calabrese, Inorg. Chim. Acta, 1976, 19, L41 CrossRef CAS.
  11. D. Coucouvanis, M. Kanatzidis, E. Simhon and N. C. Baenziger, J. Am. Chem. Soc., 1984, 104, 1874; D. Fenske, J. Meyer and K. Merzweiler, Z. Naturforsch., Teil B, 1987, 42, 1207 CAS; P. A. W. Dean, J. Vittal and N. C. Payne, Inorg. Chem., 1987, 26, 1683 CrossRef CAS; W. Tremel, B. Krebs, K. Greiwe, W. Simon, H.-O. Stephan and G. Henkel, Z. Naturforsch., Teil B, 1992, 47, 1580 CAS; H.-O. Stephan, K. Griesar, W. Haase and G. Henkel, Z. Naturforsch., Teil B, 1994, 49, 1620 CAS.
  12. (a) K. S. Hagen and R. H. Holm, J. Am. Chem. Soc., 1982, 104, 5496 CrossRef CAS; (b) M. A. Whitener, J. K. Bashkin, K. S. Hagen, J.-J. Girerd, E. Gamp and N. Edelstein, J. Am. Chem. Soc., 1986, 108, 5607 CrossRef CAS; (c) R. H. Holm, K. S. Hagen and A. D. Watson, in Chemistry for the Future, ed. H. Grünewald, Pergamon, New York, 1984, pp. 115–124 Search PubMed.
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