Ruthenium complexes of eilatin: face selectivity in octahedral geometry; synthesis of [Ru(bpy)2(eilatin)]2+ and [Ru(phen)2(eilatin)]2+

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Amira Rudi, Yoel Kashman, Dalia Gut, Fabienne Lellouche and Moshe Kol


Abstract

Eilatin, a marine alkaloid, is a potentially bifacial ligand that prefers to bind through its less hindered face in sterically demanding geometries as evident by the selective synthesis of two octahedral ruthenium complexes.


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