Solvent-free oxidation reactions with Ti-MCM-41 and TS-1 catalysts occluded in polydimethylsiloxane (PDMS) membranes

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Ivo Vankelecom, Karen Vercruysse, Nancy Moens, Rudy Parton, Jale Sudhakar Reddy and Pierre Jacobs


Abstract

The incorporation of TS-1 and Ti-MCM-41 catalysts in PDMS is proven to enable the oxidation of hexane and epoxidation of cis-cyclooctene, respectively, with high conversions under solvent-free reaction conditions.


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