Structure of an amorphous polymer electrolyte, poly(ethylene oxide)3:LiCF3SO3

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Roger Frech, Sangamithra Chintapalli, Peter G. Bruce and Colin A. Vincent


Abstract

The amorphous phase formed on melting the crystalline polymer electrolyte PEO3:LiCF3SO3 has a short-range structure in which all of the lithium ions are located within the poly(ethylene oxide) helix.


References

  1. P. Lightfoot, M. A. Mehta and P. G. Bruce, Science, 1993, 262, 883 CrossRef CAS.
  2. J. B. Thomson, Ph.D. Thesis, University of St Andrews, 1996.
  3. G. Petersen, P. Jacobsson and L. M. Torell, Electrochim. Acta, 1992, 37, 1495 CrossRef CAS.
  4. W. Huang, R. Frech and R. A. Wheeler, J. Phys. Chem., 1994, 98, 100 CrossRef CAS.
  5. J. R. Stevens and P. Jacobsen, Can. J. Chem., 1991, 69, 1980 CAS.
  6. W. Huang and R. Frech, Polymer, 1994, 35, 235 CrossRef CAS.
  7. H. Matsuura and K. Fukuhara, J. Polym. Sci. B, 1986, 24, 1383 CrossRef CAS.
  8. M. E. Ries, M. G. Breeton, J. M. Cruickshank, P. G. Klein and I. M. Ward, Macromolecules, 1995, 28, 3282 CrossRef CAS.
  9. R. Frech, S. Chintapalli, P. G. Bruce and C. A. Vincent, to be published.
  10. M. B. Armand, J. M. Chabagno and M. Duclot, Second International Meeting on Solid Electrolytes, St. Andrews, Scotland, 1978, extended abstracts 6.5 Search PubMed.
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