Proton migration on the [60]fullerene cage of
1-tert-butyl-1,4-dihydro[60]fullerene to yield the
1,2-isomer
(Note: The full text of this document is currently only available in the PDF Version )
Fiachra Banim, David J. Cardin and Peter Heath
Abstract
Proton NMR data on the base catalysed rearrangement of
1-tert-butyl-1,4-dihydro[60]fullerene to the 1,2-isomer reveal a
second order reaction and an activation energy of 56.1 kJ
mol-1.
References
P. J. Fagan, P. J. Krusic, D. H. Evans, S. A. Lerke and E. Johnston, J. Am. Chem. Soc., 1992, 114, 9697 CrossRefCAS.
T. Kitagawa, T. Tanaka, Y. Takata and K. Takeuchi, J. Org. Chem., 1995, 60, 1490 CrossRefCAS.
N. Matsuzawa, D. A. Dixon and T. Fukunaga, J. Phys. Chem., 1992, 96, 7594 CrossRefCAS.
A. Hirsch, A. Soi and H. R. Karfunkel, Angew. Chem., Int. Ed. Engl., 1992, 31, 766 CrossRef; Angew. Chem.,
1992,
104,
808 Search PubMed.
K. Choho,
G. Van Lier,
G. Lier,
G. Van de Woude and
P. Geerlings,
unpublished results.
Click here to see how this site uses Cookies. View our privacy policy here.