DOI: 10.1039/A605842F
(Paper)
Reference Section for: Chem. Commun., 1997, 365-366
From monomeric iminosilane to a monomeric aminoalane: synthesis and crystal structures
(Note: The full text of this document is currently only available in the PDF Version )
Jörg Niesmann, Uwe Klingebiel, Mathias Noltemeyer and Roland Boese
Abstract
The reaction between the iminosilane R2Si![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
NR′
[R = CMe3, R′= Si(CMe3)2Ph] 1 and
AlMe3 in n-hexane at -78 °C affords the
first monomeric aminodimethylalane
Me2AlN(R′)R″ [R″=
Si(CMe3)2Me] 2; the crystal structure of 2 is
presented.
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