Jörg Niesmann, Uwe Klingebiel, Mathias Noltemeyer and Roland Boese
The reaction between the iminosilane R2SiNR′
[R = CMe3, R′= Si(CMe3)2Ph] 1 and
AlMe3 in n-hexane at -78 °C affords the
first monomeric aminodimethylalane
Me2Al
N(R′)R″ [R″=
Si(CMe3)2Me] 2; the crystal structure of 2 is
presented.