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DOI: 10.1039/A605748I (Paper) Reference Section for: Chem. Commun., 1997, 467-468

Self-assembly directed by NH···O hydrogen bonding: a neutron study of a trilayered supramolecular array formed between 1,2-diaminoethane and benzoic acid

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Kenneth R. Adam, Ian M. Atkinson, R. Lindsay Davis, Leonard F. Lindoy, Myrna S. Mahinay, Brian J. McCool, Brian W. Skelton and Allan H. White

Abstract

The supramolecular array formed by co-crystallisation of 1,2-diaminoethane and benzoic acid is investigated by neutron diffraction; the system self-assembles into an unusual layered structure composed of two-dimensional hydrogen-bonded networks sandwiched between layers of edge-to-face stacked aromatic systems; the number of hydrogen-bond donors and acceptors is balanced in the structure.

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