Integrated Automatic Determination of Nitrate, Ammonium and Organic Carbon in Soil Samples

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Evaristo Ballesteros, Angel Ríos and Miguel Valcárcel


Abstract

An automated photometric method for the sequential determination of nitrate, ammonium and organic carbon in soils by use of a single-line flow injection assembly is reported, but differently programmed for the assay of the individual analytes. These analytes, which are determined by using suitable photometric reagents, are directly related to the nutritional properties of soil. A filtration probe was used for the continuous filtration of soil extract. The precision, expressed as RSD, was 2.0, 2.6 and 2.1% for nitrate, ammonium and organic carbon, respectively. The proposed method features a high throughput and low reagent consumption, and requires minimal sample handling. Its performance was tested in routine analyses of soil samples, all with satisfactory results.


References

  1. A. L. Page, R. H. Miller and D. R. Keeney, Methods of Soil Analysis. Part 2. Chemical and Microbiological Properties, American Society of Agronomy and Soil Science Society of America, Madison, WI, 2nd edn., 1982 Search PubMed.
  2. M. Valcárcel and M. D. Luque de Castro, Flow Injection Analysis: Principles and Applications, Ellis Horwood, Chichester, 1987 Search PubMed.
  3. J. Růžička and E. H. Hansen, Flow Injection Analysis, Wiley, New York, 2nd edn., 1988 Search PubMed.
  4. M. Valcárcel and M. D. Luque de Castro, Fresenius' J. Anal. Chem., 1990, 337, 662 CrossRef CAS.
  5. F. Lazaro, M. D. Luque de Castro and M. Valcárcel, Anal. Chim. Acta, 1991, 242, 283 CrossRef CAS.
  6. M. A. Z. Arruda, M. Gallego and M. Valcárcel, J. Anal. At. Spectrom., 1995, 10, 501 RSC.
  7. S. McLeod, Anal. Chim. Acta, 1992, 266, 107 CrossRef CAS.
  8. Z. Zhi, A. Ríos and M. Valcárcel, J. Environ. Anal. Chem., 1994, 57, 279 Search PubMed.
  9. M. D. Luque de Castro and M. Valcárcel, Analyst, 1984, 109, 413 RSC.
  10. A. Ríos, M. D. Luque de Castro and M. Valcárcel, Analyst, 1984, 109, 1487 RSC.
  11. F. Cañete, A. Ríos, M. D. Luque de Castro and M. Valcárcel, Analyst, 1988, 113, 739 RSC.
  12. A. Farran, J. L. Cortina, J. de Pablo and D. Barceló, Anal. Chim. Acta, 1990, 234, 119 CrossRef CAS.
  13. E. Ballesteros, M. Gallego and M. Valcárcel, Anal. Chem., 1990, 62, 1587 CrossRef CAS.
  14. E. Ballesteros, M. Gallego and M. Valcárcel, Anal. Chem., 1993, 65, 1773 CrossRef CAS.
  15. S. J. Bajic and B. Jaselskis, Talanta, 1985, 32, 115 CrossRef CAS.
  16. Z. Marczenko, Spectrophotometric Determination of Elements, Ellis Horwood, Chichester, 1976 Search PubMed.
  17. A. Kojlo and E. Gorodkiewicz, Anal. Chim. Acta, 1995, 302, 283 CrossRef CAS.
  18. M. Windholz, The Merck Index. An Encyclopedia of Chemicals, Drugs and Biologicals, Merck, Rahway, NJ, 10th edn., 1983 Search PubMed.
  19. Standard Methods for the Examination of Water and Wastewater, ed. Greenberg, A. E., Connors, J. J., and Jenkins, D., American Public Health Association, Washington, DC, 15th edn., 1980, pp. 370–373 Search PubMed.
  20. B. Bermúdez, A. Ríos, M. D. Luque de Castro and M. Valcárcel, Talanta, 1988, 35, 810 CrossRef.
  21. F. J. Krug, J. Růžička and E. H. Hansen, Analyst, 1979, 104, 47 RSC.
  22. Z. Zhi, A. Ríos and M. Valcárcel, Anal. Chim. Acta, 1994, 293, 163 CrossRef CAS.
  23. G. Schulze, C. Y. Liu, M. Brodowski, O. Elsholz, W. Frenzel and J. Möller, Anal. Chim. Acta, 1988, 214, 121 CrossRef CAS.
  24. A. Cerdà, M. T. Oms, R. Forteza and V. Cerdà, Anal. Chin. Acta, 1995, 311, 165 Search PubMed.
  25. J. R. Sims and V. A. Haby, Soil Sci., 1971, 112, 137 CrossRef CAS.
  26. A. J. Kempers, Geoderma, 1974, 12, 201 CrossRef CAS.
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