Universal Calibration Strategy for Laser Ablation Inductively Coupled Plasma Mass Spectrometry Based on the Use of Aqueous Standards With Modified Absorption Coefficients

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Barrie J. Masters and Barry L. Sharp


Abstract

This paper describes a calibration strategy for laser ablation ICP-MS based on the use of aqueous standards with modified absorption coefficients. The design of the ablation system and standard operating conditions are described. Initial studies were performed to characterise the behaviour of the calibration standards. Validation of the calibration procedure was performed using certified NIST reference materials. Future work will involve application of the calibration procedure to the analysis of biological materials.


References

  1. M. Thompson, J. E. Goulter and F. Sieper, Analyst, 1981, 106, 32 RSC.
  2. A. A. Van Heuzen, Spectrochim. Acta, Part B, 1991, 46, 1803 CrossRef.
  3. A. A. Van Heuzen, Spectrochim. Acta, Part B, 1991, 46, 1819 CrossRef.
  4. W. T. Perkins, R. Fuge and N. J. G. Pearce, J. Anal. At. Spectrom., 1991, 6, 445 RSC.
  5. N. J. G. Pearce, W. T. Perkins and R. Fuge, J. Anal. At. Spectrom., 1992, 7, 595 RSC.
  6. J. G. Williams and K. E. Jarvis, J. Anal. At. Spectrom., 1993, 8, 25 RSC.
  7. P. J. Fordham, J. W. Gramshaw, L. Castle, H. M. Crews, D. Thompson, S. J. Parry and E. McCurdy, J. Anal. At. Spectrom., 1995, 10, 303 RSC.
  8. M. Thompson, S. Chenery and L. Brett, J. Anal. At. Spectrom., 1989, 4, 11 RSC.
  9. Y. Iida, A. Tsuge, Y. Uwamino, H. Morikawa and T. Ishizuka, J. Anal. At. Spectrom., 1991, 6, 541 RSC.
  10. S. Chenery and J. M. Cook, J. Anal. At. Spectrom., 1993, 8, 299 RSC.
  11. J. W. Hager, Anal. Chem., 1989, 61, 1243 CrossRef CAS.
  12. H. P. Longerich, D. Gunther and S. E. Jackson, Fresenius J. Anal. Chem., 1996, 355, 538 CAS.
  13. N. J. G. Pearce, W. T. Perkins, J. A. Westgate, M. P. Gorton, S. E. Jackson, C. R. Neal and S. P. Chenery, Geostand. Newsl., 1997, 21 CAS in the press.
  14. P. Dyer, personal communication, 20 June 1995, Department of Applied Physics, University of Hull, UK.
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