Flash Species-selective Analysis by Multicapillary Gas Chromatography with Microwave Induced Plasma Atomic Spectrometric Detection

(Note: The full text of this document is currently only available in the PDF Version )

Vincent O. Schmitt, Isaac Rodriguez Pereiro and Ryszard Łobiński


Abstract

Multicapillary column isothermal gas chromatography with element-selective detection has been shown to allow the ultra-rapid (<30 s instead of about 10 min) analysis of non-polar compounds with boiling-points of 200–300 °C, without sacrificing the resolution and efficiency of conventional capillary GC with oven temperature gradient programming. An example of speciation analysis for butyltin compounds in a PACS-1 certified reference sediment is shown.


References

  1. Metals and their Compounds in the Environment, ed. Merian, E., VCH, Weinheim, Germany, 1991 Search PubMed.
  2. Trace Element Speciation: Analytical Methods and Problems, ed. Batley, G. E., CRC Press, Boca Raton, FL, USA, 1987 Search PubMed.
  3. Trace Metal Analysis and Speciation, ed. Krull, I. K., Elsevier, Amsterdam, The Netherlands, 1991 Search PubMed.
  4. Environmental Analysis Using Chromatography Interfaced with Atomic Spectroscopy, ed. Harrison, R. M., and Rapsomanikis, S., Ellis Horwood, Chichester, UK, 1989 Search PubMed.
  5. N. P. Vela, L. K. Olson and J. A. Caruso, Anal. Chem., 1993, 65, 585A CAS.
  6. Element-specific Chromatographic Detection by Atomic Emission Spectroscopy, ed. Uden, P., American Chemical Society, Washington DC, USA, 1992 Search PubMed.
  7. L. Ebdon, S. Hill and R. W. Ward, Analyst, 1986, 111, 1113 RSC.
  8. R. Łobiński, Analusis, 1994, 22, 37 CAS.
  9. R. Łobiński and F. C. Adams, Spectrochim. Acta Rev., in the press Search PubMed.
  10. J. Szpunar, V. O. Schmitt, O. Donard and R. Łobiński, Trends Anal. Chem., 1996, 15, 181 CrossRef CAS.
  11. I. Rodriguez Pereiro, V. O. Schmitt, J. Szpunar, O. Donard and R. Łobiński, Anal. Chem., 1996, 68, 4135 CrossRef CAS.
  12. J. Szpunar, V. O. Schmitt, R. Łobiński and J. L. Monod, J. Anal. At. Spectrom., 1996, 11, 193 RSC.
  13. P. Uden, J. Chromatogr., 1995, 703, 393 CrossRef CAS.
  14. R. Łobiński and F. C. Adams, Trends Anal. Chem., 1993, 12, 41 CrossRef CAS.
  15. Y. K. Chau, F. Yang and M. Brown, Anal. Chim. Acta, 1995, 304, 85 CrossRef CAS.
  16. M. Ceulemans and F. C. Adams, Anal. Chim. Acta, 1995, 317, 161 CrossRef.
Click here to see how this site uses Cookies. View our privacy policy here.