Solid-phase Extraction of a Triazine Herbicide Using a Molecularly Imprinted Synthetic Receptor

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Jun Matsui, Makoto Okada, Makoto Tsuruoka and Toshifumi Takeuchi


Abstract

A molecularly imprinted synthetic polymer receptor selective for triazine herbicides was prepared by suspension polymerization, and was applied to the specific solid-phase extraction of simazine, one of the triazine herbicides, from water. The procedure involves the reversed-phase mode operation of the synthetic receptor to retain lipophilic agrochemicals, including simazine, in water, followed by affinity separation based on hydrogen bonding which exhibits selective retention of simazine, eluting the other undesired compounds. The solid-phase extraction yielded a 56 times concentrated simazine solution with a recovery rate of 91%.


References

  1. J. Sherma, Anal. Chem., 1993, 65, 40R CAS.
  2. Z. Cai, V. M. S. Ramanujam, D. E. Giblin, M. L. Gross and R. F. Spalding, Anal. Chem., 1993, 65, 21 CrossRef CAS.
  3. D. S. Aga and E. M. Thurman, Anal. Chem., 1993, 65, 2894 CrossRef CAS.
  4. A. Di Corcia, R. Samperi, A. Marcomini and S. Stelluto, Anal. Chem., 1993, 65, 907 CrossRef CAS.
  5. M. Berg, S. R. Müller and R. P. Schwarzenbach, Anal. Chem., 1995, 67, 1860 CrossRef CAS.
  6. K. Mosbach and O. Ramström, Bio/Technology, 1996, 14, 163 Search PubMed.
  7. R. J. Ansell, D. Kriz and K. Mosbach, Curr. Opin. Biotechnol., 1996, 7, 89 CrossRef CAS.
  8. G. Wulff, Angew. Chem. Int. Ed. Engl., 1995, 34, 1812 CrossRef CAS.
  9. S. Vidyasankar and F. H. Arnold, Curr. Opin. Biotechnol., 1995, 6, 218 CrossRef CAS.
  10. K. J. Shea, Trends Polym. Sci., 1994, 2, 166 Search PubMed.
  11. T. Takeuchi and J. Matsui, Acta Polym., 1996, 47, 471 CrossRef CAS.
  12. J. Matsui, Y. Miyoshi, O. Doblhoff-Dier and T. Takeuchi, Anal. Chem., 1995, 67, 4404 CrossRef CAS.
  13. J. Matsui, Y. Miyoshi and T. Takeuchi, Chem. Lett., 1995, 1007 CAS.
  14. M. T. Muldoon and L. H. Stanker, J. Agric. Food Chem., 1995, 43, 1424 CrossRef CAS.
  15. M. Siemann, L. I. Andersson and K. Mosbach, J. Agric. Food Chem., 1996, 44, 141 CrossRef CAS.
  16. J. Matsui, T. Kato, T. Takeuchi, M. Suzuki, K. Yokoyama, E. Tamiya and I. Karube, Anal. Chem., 1993, 65, 2223 CAS.
  17. J. Matsui, Y. Miyoshi, R. Matsui and T. Takeuchi, Anal. Sci., 1995, 11, 1017 CrossRef CAS.
  18. K. Hosoya, K. Yoshizako, N. Tanaka, K. Kimata, T. Araki and J. Haginaka, Chem. Lett., 1994, 1437 CAS.
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