Issue 10, 1996
From the journal:

Journal of the Chemical Society, Perkin Transactions 2

Paramagnetic intermediates in the photolysis of 2-methylpropanoyltripropylstannane studied by means of multinuclear CIDNP

Alexander I. Kruppa,   Marc B. Taraban,   Serge A. Svarovsky  and  Tatyana V. Leshina  

Abstract

1 H, 13C and 119Sn CIDNP studies of 2-methylpropanoyltripropylstannane Pr3SnC(O)Pri 1 photolysis in benzene have shown that its photodecomposition occurs from the triplet excited state via Sn–C (tin–carbonyl) bond cleavage. Formation of Pr3Sn˙, ˙COCHMe2 and ˙CHMe2 free radicals has been observed. Possibilities of their reactions with initial ketone and main reaction products have been discussed.

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Article information

DOI
https://doi.org/10.1039/P29960002151
Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1996, 2151-2155

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Paramagnetic intermediates in the photolysis of 2-methylpropanoyltripropylstannane studied by means of multinuclear CIDNP

A. I. Kruppa, M. B. Taraban, S. A. Svarovsky and T. V. Leshina, J. Chem. Soc., Perkin Trans. 2, 1996, 2151 DOI: 10.1039/P29960002151

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